Re-entrant-Groove-Assisted VLS Growth of Boron Carbide Five-Fold Twinned Nanowires

We report a preferential growth of boron carbide nanowires with a five-fold twinned internal structure. The nanowires are found to grow catalytically via iron boron nanoparticles, but unusually the catalytic particle is in contact with the low-energy surfaces of boron carbide with V-shaped contact lines. We propose that this catalytical growth may be caused by preferential nucleation at the re-entrant grooves due to the twinning planes, followed by rapid spreading of atomic steps. This is consistent with the observed temperature dependence of the five-fold twinned nanowire growth.     

中小口径双非球面数控抛光技术研究

针对口径Φ62 mm双凸非球面透镜,进行了数控研磨和抛光技术研究.提出了规范性的加工工艺流程,实现了中小口径双非球面元件的高效、快速抛光.根据计算机控制光学表面成型技术,采用全口径抛光和小抛头修抛的两步抛光法,在抛光中对其面形误差进行多次反馈补偿,使被加工零件表面的面形精度逐步收敛.最终两面的面形精度均小于0.5 μm,中心偏差小于0.01 mm,满足了光学系统中对非球面元件的精度要求,并且在保证有较高面形精度和较好表面光洁度的同时,解决了双非球面中心偏差和中心厚度难以控制的加工技术难题.     

环氧大豆油与丙交酯星形共聚物支化度的表征

采用凝胶色谱(GPC)/示差检测器(RI)/十八角激光光散射仪(MALLS)联用技术, 对环氧大豆油(ESO)与丙交酯形成的星形共聚物(ESO-丙交酯)的结构进行了表征。实验结果表明: 随着ESO-丙交酯星形共聚物分子量的增长, 接枝数目呈现增多趋势、支化度从0.46E-4增大到0.78E-4、支化因子从0.82减小到0.15。本研究为高分子ESO-丙交酯星形支化共聚物的研究提供了科学依据。     

9SNCR烟气脱硝工艺及CH4作添加剂的试验研究

本文介绍了在自行研制的选择性非催化还原(SNCR)烟气脱硝试验台上采用改进型TB系列喷嘴深入烟道内部逆流喷入的方式,进行了冷态混合试验和气态氨作还原剂及CH4作添加剂的热态脱硝试验.深入烟道内部的喷入方式在提高喷入气体与烟道主气流的混合效果上明显优于侧壁圆孔喷入.在NH3/NOx=1.25,反应温度为925℃时可得到82.53%的脱硝效率,有CH4作添加剂时,温度为875℃时可得到72.37%的脱硝效率.以NOx去除率高于50%为标准,温度窗口为863～937℃;有CH4作添加剂的温度窗口为803～929℃.随着氨氮比的增大NOx去除效率也增大,但在最优温度下当氨氮比大于1.0后NOx去除率的增大不再明显.随着温度的升高,达到NOx最大去除率所需的CH4添加量减小,CH4作添加剂可大大减小氨的泄漏量.     

Breather Lattice Solutions to Negative mKdV Equation

In this paper, dependent and independent variable transformations are introduced to solve the negative mKdV equation systematically by using the knowledge of elliptic equation and Jacobian elliptic functions. It is shown that different kinds of solutions can be obtained to the negative mKdV equation, including breather lattice solution and periodic wave solution.     

Introduction to the overall physics design of CSNS accelerators

The China Spallation Neutron Source (CSNS) is an accelerator-based facility. The     

High-Order Above-Threshold Ionization of H2+ in Intense Laser Field

The nonperturbative quantum electrodynamies method proposed by Fu et al. [Phys. Rev. A 75 （2007） 063419] is employed to study the high-order above-threshold ionization （ATI） of a diatomic molecule. Based on this frequency-domain theory, the high-order ATI process can be regarded as ATI followed by laser-assisted collision, where the total transition amplitude is the coherent summation of the contributions from each ATI channel. The angular-resolved ATI spectrum, which agrees with the results by Becket et al. based on the time-domain method, is obtained by this frequency domain theory. Furthermore, it is demonstrated that the interference characteristics representing the molecular structure in the ATI spectrum originates from the recollision of the electron with two-centre ion in each ATI channel.     

Mn掺杂ZnO纳米棒阵列的制备及其磁学性质研究

在95 ℃条件下通过水热方法制备出垂直于ITO基底高密度均匀生长的Mn掺杂ZnO（ZnO：Mn）纳米棒阵列. 纳米棒的直径约为100纳米,长约1微米,且沿［001］方向生长. XRD和XPS结果证实了Mn以替位方式掺杂到纳米棒中,并且掺杂浓度与反应物中的Mn离子浓度似呈正比关系. 所制备的ZnO：Mn纳米棒在室温均有铁磁性,其饱和磁化强度随反应物中Mn离子浓度的提高,饱和磁化强度呈现出先增大,5at.%时达到最大值,0.11 emu/g,然后减小. 铁磁性来源于取代Zn离子的Mn离子之间的铁磁交换相互作用.     

高度有序TiO2纳米管阵列的制备及其生长机制

采用金属钛片和石墨分别作为阳极和阴极,氢氟酸和醋酸的混合溶液为电解液,通过阳极氧化法制备高度有序的TiO2 纳米管阵列. 经过场发射扫描电子显微镜(FESEM), X-射线电子衍射仪分别对样品的形貌,结构进行了研究. 结果表明,TiO2 纳米管的尺寸,形貌都随着外加电压、反应时间的变化而变化;随着退火温度的提高,TiO2 纳米管的结构逐渐由锐钛矿相向金红石相转变. 另外,我们讨论了TiO2 纳米管阵列形成机制.     

反演波段对DOAS测量大气中O_3的性能影响研究

臭氧(O3)浓度通常被认为是一个地方污染水平的基准,所以其绝对值的准确性至关藿要.在差分光学吸收光谱技术(DOAS)对O3的测量过程中,光谱反演波段的选择可直接决定O3浓度的测量准确度.文章主要研究了在不同光谱波段O3特征吸收结构和差分光学厚度(D')的不同,在不同光谱波段O3浓度反演的干扰来源以及影响程度,确定了实际检测时大气消光对不同波段光强的影响,最后通过对多种污染物标准气体进行了同时临测,计算出标准气体在不同光谱分辨率不同O3浓度时的测量误差,确定了对O3的最适用光谱波段范围.在此波段既能够实现对痕量气体的准确定性定量,又能达到测量所需要的高灵敏度,强选择性和适用的时间分辨率.